Coordination Chemistry

  1. Thermodynamics and Kinetics
    1. Complex Stability
      1. Thermodynamic Stability
        1. Formation Constants
          1. Stepwise Constants
            1. Overall Constants
            2. Factors Affecting Stability
              1. Chelate Effect
                1. Macrocyclic Effect
                  1. Steric Effects
                    1. Electronic Effects
                  2. Kinetic Properties
                    1. Labile and Inert Complexes
                      1. Rate Constants
                        1. Activation Parameters
                        2. Reaction Mechanisms
                          1. Ligand Substitution
                            1. Octahedral Complexes
                              1. Dissociative Mechanism
                                1. Associative Mechanism
                                  1. Interchange Mechanisms
                                  2. Square Planar Complexes
                                    1. Trans Effect
                                      1. Trans Influence
                                    2. Electron Transfer Reactions
                                      1. Outer Sphere Mechanism
                                        1. Inner Sphere Mechanism
                                          1. Marcus Theory
                                          2. Photochemical Reactions
                                            1. Ligand Photosubstitution
                                              1. Photoinduced Electron Transfer

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                                          8. Magnetic Properties

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                                          10. Applications