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Chemistry
Specialized Chemistry
Coordination Chemistry
1. Introduction to Coordination Chemistry
2. Ligands
3. Nomenclature of Coordination Compounds
4. Isomerism in Coordination Complexes
5. Structure and Geometry
6. Bonding Theories
7. Electronic Spectroscopy
8. Magnetic Properties
9. Thermodynamics and Kinetics
10. Applications
11. Organometallic Chemistry
7.
Electronic Spectroscopy
7.1.
Principles
7.1.1.
Light Absorption
7.1.2.
Electronic Transitions
7.1.3.
Beer-Lambert Law
7.2.
Selection Rules
7.2.1.
Spin Selection Rule
7.2.2.
Laporte Selection Rule
7.2.3.
Relaxation of Selection Rules
7.3.
Types of Electronic Transitions
7.3.1.
d-d Transitions
7.3.1.1.
Allowed Transitions
7.3.1.2.
Forbidden Transitions
7.3.2.
Charge Transfer Transitions
7.3.2.1.
Ligand-to-Metal Charge Transfer
7.3.2.2.
Metal-to-Ligand Charge Transfer
7.3.2.3.
Metal-to-Metal Charge Transfer
7.4.
Spectral Interpretation
7.4.1.
Orgel Diagrams
7.4.2.
Tanabe-Sugano Diagrams
7.4.3.
Parameter Determination
7.4.3.1.
Crystal Field Splitting
7.4.3.2.
Racah Parameters
7.4.4.
Band Assignment
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6. Bonding Theories
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8. Magnetic Properties