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Polymer Science and Engineering
1. Introduction to Polymer Science and Engineering
2. Polymer Synthesis
3. Polymer Structure and Molecular Weight
4. Polymer Morphology and Solid-State Properties
5. Physical and Mechanical Properties
6. Polymer Solutions and Blends
7. Polymer Processing and Rheology
8. Polymer Characterization Techniques
9. Advanced Topics and Applications
Polymer Solutions and Blends
Polymer Solubility
Thermodynamics of Polymer Dissolution
Gibbs Free Energy of Mixing
Entropy and Enthalpy Contributions
Chemical Potential
Flory-Huggins Theory
Interaction Parameter
Limitations of the Theory
Phase Separation Prediction
Solubility Parameters
Hildebrand Solubility Parameter
Hansen Solubility Parameters
Dispersion Component
Polar Component
Hydrogen Bonding Component
Polymer Solutions
Concentration Regimes
Dilute Regime
Coil Expansion
Isolated Chains
Semi-dilute Regime
Overlap Concentration
Entanglement Onset
Concentrated Regime
Entanglement Effects
Melt-like Behavior
Solution Viscosity
Intrinsic Viscosity
Concentration Dependence
Huggins Equation
Osmotic Pressure
Virial Expansion
Second Virial Coefficient
Polymer Blends and Alloys
Miscibility and Immiscibility
Criteria for Miscibility
Phase Separation
Spinodal Decomposition
Phase Behavior and Phase Diagrams
Upper Critical Solution Temperature
Lower Critical Solution Temperature
Binodal and Spinodal Curves
Compatibilization Techniques
Block Copolymer Compatibilizers
Graft Copolymer Compatibilizers
Reactive Blending
Properties of Polymer Blends
Mechanical Properties
Thermal Properties
Morphology
Interfacial Adhesion
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7. Polymer Processing and Rheology