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Chemistry
Fundamental Chemistry
Inorganic Chemistry
1. Foundational Principles of Inorganic Chemistry
2. Chemical Bonding and Molecular Structure
3. Molecular Symmetry and Group Theory
4. Acids, Bases, and Solvents
5. Oxidation and Reduction (Redox) Chemistry
6. Chemistry of the Main Group Elements
7. Coordination Chemistry of Transition Metals
8. Reaction Mechanisms of Coordination Compounds
9. Organometallic Chemistry
10. Solid-State Inorganic Chemistry
11. Bioinorganic Chemistry
12. Special Topics
8.
Reaction Mechanisms of Coordination Compounds
8.1.
Ligand Substitution Reactions
8.1.1.
Mechanistic Pathways
8.1.1.1.
Associative (A) Mechanism
8.1.1.2.
Dissociative (D) Mechanism
8.1.1.3.
Interchange Mechanisms
8.1.1.3.1.
Associative Interchange (Ia)
8.1.1.3.2.
Dissociative Interchange (Id)
8.1.2.
Factors Affecting Substitution Rates
8.1.2.1.
Nature of the Metal Ion
8.1.2.2.
Nature of the Leaving Ligand
8.1.2.3.
Nature of the Entering Ligand
8.1.3.
The Trans Effect
8.1.3.1.
Definition and Examples
8.1.3.2.
Trans-Directing Series
8.1.3.3.
Applications in Synthesis
8.2.
Redox Reactions of Complexes
8.2.1.
Outer Sphere Mechanism
8.2.1.1.
Marcus Theory
8.2.1.2.
Reorganization Energy
8.2.2.
Inner Sphere Mechanism
8.2.2.1.
Bridging Ligands
8.2.2.2.
Electron Transfer Pathways
8.2.3.
Mixed Mechanisms
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7. Coordination Chemistry of Transition Metals
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9. Organometallic Chemistry