Chemical Kinetics and Catalysis
Definition and Consequences
Effect on Reaction Pathways
Geminate Recombination
Diffusion Rate Limitation
Smoluchowski Equation
Encounter Complex Formation
Diffusion Coefficients
Energy Barrier Limitation
Comparison with Diffusion-Controlled Reactions
Mixed Control Regimes
Effect on Ionic Reactions
Effect on Non-Ionic Reactions
Solvent Polarity Scales
Impact on Diffusion Rates
Kramers Theory
Debye-Hückel Theory
Primary Salt Effects
Secondary Salt Effects
Activity Coefficients
Volume of Activation
High-Pressure Kinetics
Specific Solvation
Hydrogen Bonding
Ion Pairing
Solvent Reorganization
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4. Theories of Reaction Rates
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6. Introduction to Catalysis